Among the 20 most expensive cards from this set, 14 of them are absolutely gorgeous Special Illustration Rares. This expansion also introduces Poké Ball and Master Ball parallel cards which sparkle with personality.

In this article, we'll explore the top 20 most valuable cards from the Prismatic Evolutions set and discuss factors that contribute to their high market value, and I have listed the best places to buy and sell these new additions to the Pokémon TCG!

If there’s one card that defines Prismatic Evolutions, it’s the irresistibly captivating Umbreon ex Special Illustration Rare. Following in the footsteps of Evolving Skies’ legendary "Moonbreon," this new iteration—already dubbed "Sunbreon" by collectors—has cemented itself as the undisputed chase card of Scarlet & Violet. And with confirmed sales that rival or even surpass its predecessor, its dominance in the market isn’t even a question.

Will its price hold as more copies enter circulation? That remains to be seen, but if history tells us anything, Umbreon has a way of defying expectations and maintaining its throne as one of the most sought‐after Pokémon in the TCG.

While Umbreon may be the crown jewel of Prismatic Evolutions, Sylveon ex Special Illustration Rare is carving out its own place as a top‐tier chase card. Early prices soared as high as $700, an eye‐watering number for a freshly released card.

The art embraces everything that makes Sylveon iconic: soft pinks, blues, and whites swirling in dreamy, ribbon‐filled pastels. If you’re lucky enough to pull one, sleeve it immediately because this one’s a keeper!

The Espeon ex Special Illustration Rare features bright and elegant artwork and lives up to Espeon’s history as one of the most consistently valuable Eeveelutions. This is one of the most expensive Espeon cards, second only to the Unseen Forces Espeon ex Holo.

Leafeon ex Special Illustration Rare stands out with a majestic woodland backdrop, contrasting its more whimsical Eeveelution counterparts. This is now the most expensive Leafeon card ever printed, surpassing even Evolving Skies’ Leafeon VMAX!

Flareon ex Special Illustration Rare burns bright with a striking flame design and intense energy! It is currently the second most valuable Flareon card ever printed, which is impressive given Flareon’s long history in the TCG.

Glaceon ex Special Illustration Rare showcases a stunning geometric ice-like backdrop that makes it a top-tier chase card. Its value has even surpassed that of Evolving Skies' alternate-art Glaceon VMAX.

The Vaporeon ex Special Illustration Rare blends abstract artistry with a beautiful underwater aesthetic, making it a must-have for fans of Pokémon art. Its value is second only to the iconic Vaporeon Gold Star.

The Master Ball version of Umbreon is Prismatic Evolutions’ most expensive non-SIR card. Master Ball cards appear once in every 20 packs, making Umbreon Master Ball Foil a true gem for collectors.

Jolteon ex Special Illustration Rare brings its lightning-fast energy to life with dramatic vanishing point artwork, capturing the essence of its electric nature. A must-have for Jolteon enthusiasts!

Eevee ex Special Illustration Rare is a charming representation of the beloved Pokémon, quickly rising as one of the most valuable Eevee cards in existence. Its adorable design makes it a favorite among collectors.